I watched it all. I learned things that I plan to use. Thanks for that.
Couple tips I noticed, though. For one, you made your fill hole conical, but that was what made it really tough to get your top half of the mold off the part. A cylinder there would have been better. Any reason why you couldn't have used a tiny amount of clay to bridge to a hard cylinder (like a tiny dowel rod or even better, some kind of slick metal rod)? I guess that may not have wanted to stand up easily, but you could have probably run some supports from the sides of your box to hold it. Probably only important if you really *are* planning to use your mold to make a lot of a thing.
Second, an easy way to find out your urethane volume is to get the volume of your part first (duh). An easy way to do that is displacement...fill a measuring cup big enough to hold your part with enough water you can submerge it. Measure the water before and after submerging, subtract, and you know your part volume. Then obviously mix a tad more than that.
I happen to have a 3D printer, and I can see this being a lot faster for folks who want to make a LOT of a part since 3D printer filament is expensive and 3D printers are pretty dang slow. (And you mention in the video that you can get a stronger part, too...but can't you also do *softer* parts out of rubber-like materials?)
I also happen to have a laser cutter, and can see a good use case for:
https://www.makercase.com/
Use that to laser cut an acrylic box of the perfect size for your part. I think I'd try finger style and then still just use Gorilla tape to hold it together. The edges are so clean when laser cut that I *think* the mold liquid wouldn't seep any.
Anyway, good stuff. Nicely done video, too.
--Donnie